Improving the Conversion of Biomass in Catalytic Pyrolysis via Intensification of Biomass—Catalyst Contact by Co-Pressing
نویسندگان
چکیده
Biomass pyrolysis is a promising technology for fuel and chemical production from an abundant renewable source. It takes place usually in two stages; non-catalytic with further catalytic upgrading of the formed oil. The direct biomass reduces temperature, increase yield to target products improves their quality. However, such one-stage process contact between solid catalyst particles poor leading excessively high degree pure thermal reactions. aim this study was enhance catalyst-biomass via co-pressing as pre-treatment method. Catalytic components HY USY zeolites studied using thermogravimetric analysis (TGA), well experiments reactor. liquid coke yields were characterized gas chromatography, TGA respectively. results showed that degradation co-pressed cellulose occurred at lower temperatures compared degradation, non-pretreated cellulose. All produced better method, where increased while coke/char decreased. Bio-oil mainly heavier fractions, presence medium fraction within gasoline range. For hemicellulose pyrolysis, catalysts had similar effects enhancing lighter fraction, but specifically, higher selectivity middle has percentage fraction. Using both catalysts, best effect eliminating improving range Spent sample concentrations due shorter residence times volatiles, which suppresses occurrence secondary reactions formations.
منابع مشابه
study of cohesive devices in the textbook of english for the students of apsychology by rastegarpour
this study investigates the cohesive devices used in the textbook of english for the students of psychology. the research questions and hypotheses in the present study are based on what frequency and distribution of grammatical and lexical cohesive devices are. then, to answer the questions all grammatical and lexical cohesive devices in reading comprehension passages from 6 units of 21units th...
comparison of catalytic activity of heteropoly compounds in the synthesis of bis(indolyl)alkanes.
heteropoly acids (hpa) and their salts have advantages as catalysts which make them both economically and environmentally attractive, strong br?nsted acidity, exhibiting fast reversible multi-electron redox transformations under rather mild conditions, very high solubility in polar solvents, fairly high thermal stability in the solid states, and efficient oxidizing ability, so that they are imp...
15 صفحه اولKinetics of biomass catalytic pyrolysis.
The Coats-Redfern method was used to analyze the kinetic characteristics of biomass catalytic pyrolysis, indicating that it can be described by multi-step reactions, rather than as a simple first-order reaction. Friedman model-free calculations were used to describe the starting reaction types and the corresponding initial kinetic parameters. Finally, nonlinear regression of biomass catalytic p...
متن کاملBiomass Conversion to Produce Hydrocarbon Liquid Fuel Via Hot-vapor Filtered Fast Pyrolysis and Catalytic Hydrotreating
Lignocellulosic biomass conversion to produce biofuels has received significant attention because of the quest for a replacement for fossil fuels. Among the various thermochemical and biochemical routes, fast pyrolysis followed by catalytic hydrotreating is considered to be a promising near-term opportunity. This paper reports on experimental methods used 1) at the National Renewable Energy Lab...
متن کاملcontrol of the optical properties of nanoparticles by laser fields
در این پایان نامه، درهمتنیدگی بین یک سیستم نقطه کوانتومی دوگانه(مولکول نقطه کوانتومی) و میدان مورد مطالعه قرار گرفته است. از آنتروپی ون نیومن به عنوان ابزاری برای بررسی درهمتنیدگی بین اتم و میدان استفاده شده و تاثیر پارامترهای مختلف، نظیر تونل زنی(که توسط تغییر ولتاژ ایجاد می شود)، شدت میدان و نسبت دو گسیل خودبخودی بر رفتار درجه درهمتنیدگی سیستم بررسی شده اشت.با تغییر هر یک از این پارامترها، در...
15 صفحه اولذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Catalysts
سال: 2021
ISSN: ['2073-4344']
DOI: https://doi.org/10.3390/catal11070805